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431 Stainless Steel

431 Stainless Steel is a high-chromium, low-nickel martensitic stainless steel that is heat-treatable to provide high tensile strength and moderate corrosion resistance. It is particularly suited for marine applications, pump shafts, aircraft components, and fasteners, where high strength, toughness, and corrosion resistance are crucial.

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Chemical Composition of 431 Stainless Steel

Element Composition (%)
Carbon (C) 0.12 – 0.20
Chromium (Cr) 15.0 – 18.0
Nickel (Ni) 1.25 – 3.0
Manganese (Mn) ≤ 1.00
Silicon (Si) ≤ 1.00
Phosphorus (P) ≤ 0.040
Sulfur (S) ≤ 0.030
Iron (Fe) Balance

Technical Specifications of 431 Stainless Steel

Physical Properties

Property Metric Imperial
Density 7.8 g/cm³ 0.282 lb/in³
Elastic Modulus 200 GPa 29.0 x 10⁶ psi
Thermal Conductivity (at 100°C) 20.2 W/m·K 11.7 BTU/hr·ft·°F
Coefficient of Thermal Expansion 10.2 µm/m°C 5.6 x 10⁻⁶ in/in°F
Specific Heat 460 J/kg·K 0.11 BTU/lb·°F
Electrical Resistivity 720 nΩ·m 28.3 µΩ·in
Melting Point 1482°C 2700°F

Mechanical Properties

Condition Tensile Strength (MPa) Yield Strength (MPa) Elongation (%) Hardness (HB)
Annealed 862 655 20 285
Tempered (250°C) 1370 1030 16 410
Tempered (650°C) 920 690 20 270
Tempered (1020°C, quenched) 940 750 19 280

Thermal Properties

Property Metric Imperial
Thermal Conductivity 20.2 W/m·K at 100°C 11.7 BTU/hr·ft·°F
Coefficient of Thermal Expansion 10.2 µm/m°C 5.6 x 10⁻⁶ in/in°F
Melting Point 1482°C 2700°F

Electrical Properties

Property Metric Imperial
Electrical Resistivity 720 nΩ·m 28.3 µΩ·in

Product Specifications by Solitaire Steel & Engineering LLP

Product Type Standards Sizes Types Applications
Sheets & Plates ASTM A276 Thickness: 1.5mm – 50mm Hot Rolled, Cold Rolled Marine components, fasteners
Pipes & Tubes ASTM A268 Diameter: 6mm – 1200mm Seamless, Welded Industrial fluid systems, pump shafts
Bars ASTM A276 Diameter: up to 100mm Round, Square, Hex Shafts, fasteners, pump components
Angles, Channels, Beams ASTM A484 Custom sizes available L-Angles, U-Channels, I-Beams Structural marine and industrial use
Fittings ASTM A403 Size: 1/2″ – 72″ Buttweld, Socket Weld Marine and industrial assemblies

Processing and Fabrication Properties of 431 Stainless Steel

  • Forming: Generally suited for forming operations, though may require advanced tooling due to its hardness.
  • Welding: Not recommended in the hardened and tempered state. If required, preheating to 200-300°C and slow cooling are necessary.
  • Heat Treatment:
    • Annealing: Process-annealed at 620-660°C, then air-cooled.
    • Hardening: Heat to 950-1020°C, oil-quench, and temper immediately.
    • Tempering: Typically tempered between 590-680°C for a balance of strength and ductility.
  • Machinability: Easily machinable in the annealed state; challenging in the hardened state.

Applications of 431 Stainless Steel

The high strength, hardness, and moderate corrosion resistance of 431 Stainless Steel make it ideal for:

  • Marine Equipment: Used in pump shafts, propeller shafts, and other marine components.
  • Industrial Fasteners: Ideal for high-strength bolts, nuts, and studs.
  • Aircraft Parts: Common in the manufacturing of shafts, axles, and other high-stress components.
  • Laboratory Equipment: Suitable for components requiring high hardness and corrosion resistance.

431 Stainless Steel vs. Other Grades

431 Stainless Steel provides higher tensile strength and better corrosion resistance compared to other martensitic grades like 410. However, compared to austenitic grades, 431 has lower overall corrosion resistance but higher mechanical strength, making it suitable for mechanical applications in mildly corrosive environments.